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See also Defragmentation wars.
Defragmenting of Unix/Linux disks is usually not considered to be necessary, not because Unx file systems are necessarily any better than their Windows counterparts, but because Unix systems are usually multi-user and disk access HAS to be fragmented.
At one time, a company named Crocodile made a disk defragmentation tool for Unix. They, and probably every other company that has tried this market, are no longer selling this product.
Crocodile used to be available from http://www.stallion.com. I have no idea of current status; their Web site seems to be having problems just no.
IMHO, a better way to defrag (if you need to at all, and very few Unix systems need to) is to use a product like Edge: http://www.microlite.com to reinstall.
However, people will insist that they need to defrag. Others will say, sure, but you'll need to do it constantly so why bother; http://groups.google.com/groups?selm=10109071555.aa21238@wecan.com.
http://groups.google.com/groups?hl=en&lr=&ie=UTF-8&selm=GJAyp2.vqo%40wjv.com discusses SCSI elevator seeks in conjunction with this. The argument is that SCSI drives optimize disk block access by resorting recent disk block requests for efficient access.

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